Experiments into nuclear structure have found that the total mass of a nucleus is?less?than the sum of the masses of its constituent nucleons
This difference in mass is known as the?mass defect
Mass defect is defined as:
The difference between an atom's mass and the sum of the masses of its protons and neutrons
The mass defect Δm of a nucleus can be calculated using:
Δm = Zmp?+ (A – Z)mn?– mtotal
Where:
Z?= proton number
A?= nucleon number
mp?= mass of a proton (kg)
mn?= mass of a neutron (kg)
mtotal?= measured mass of the nucleus (kg)
A system of separated nucleons has a greater mass than a system of bound nucleons
Due to the equivalence of mass and energy, this decrease in mass implies that energy is released in the process
Since nuclei are made up of neutrons and protons, there are forces of repulsion between the positive protons
Therefore, it takes energy, ie. the binding energy, to hold nucleons together as a nucleus
Binding energy is defined as:
The energy released when a nucleus forms from constituent nucleons
OR
The (minimum) energy needed to break a nucleus up into its constituent nucleons (protons and neutrons)
Energy and mass are proportional, so, the total energy of a nucleus is less than the sum of the energies of its constituent nucleons
The formation of a nucleus from a system of isolated protons and neutrons is therefore an exothermic reaction - meaning that it releases energy
This can be calculated using the equation:
E?= Δmc2
Exam Tip
Avoid describing the binding energy as the energy stored in the nucleus – this is not correct – it is energy that must be put into the nucleus to pull it apart.
Calculating Mass Defect & Nuclear Binding Energy
Binding energy can often be described per nucleon
This is simply found by dividing the relevant binding energy by the number of nucleons in the nucleus
Worked Example
The binding energy per nucleon is 7.98 MeV for an atom of Oxygen-16 (16O).
Determine an approximate value for the energy required, in MeV, to completely separate the nucleons of this atom.
Step 1: List the known quantities
Binding energy per nucleon,?E?= 7.98 MeV
Step 2: State the number of nucleons
The number of nucleons is 8 protons and 8 neutrons, therefore 16 nucleons in total
Step 3: Find the total binding energy
The binding energy for oxygen-16 is:
7.98 × 16 = 127.7 MeV
Step 4: State the final answer
The approximate total energy needed to completely separate this nucleus is?127.7 MeV
Worked Example
Calculate the binding energy per nucleon, in MeV, for the radioactive isotope potassium-40 (19K).
You may use the following data:
Nuclear mass of potassium-40 = 39.953 548 u
Mass of one neutron = 1.008 665 u
Mass of one proton = 1.007 276 u
Step 1: Identify the number of protons and neutrons in potassium-40